Looks like someone has plugged a hole with brazed silicon bronze. It's a relic helmet so probably someone was aiming to restore it, maybe fill a hole and rust pitting and paint it. But the brazing was a far as it went.
Unfortunately, the pictures didn't show that the helmet has a really big rusty hole on the top... so i don't think the restoration of a helmet in such poor condition would have started by filling a small pit.
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